o'danielite

TSNB256
Mineral
Second oxidation zoneThird oxidation zoneSupergene
O'danielite: Tiny trapezoidal orange crystals (to 0.15 mm) in quartz (locally coloured blue by stranskiite). 9 mm field of view. MGMH Collection 2022.4.8314L.
O'danielite: Tiny trapezoidal orange crystals (to 0.15 mm) in quartz (locally coloured blue by stranskiite). 9 mm field of view. MGMH Collection 2022.4.8314L.
Image Credit: Malcolm Southwood.

Mineral Species

o'danielite

Type Locality

Yes

Composition

Na☐ZnZn2(AsO4)[AsO3(OH)]2

Crystal System

Monoclinic

Status at Tsumeb

Confirmed

Abundance

Extremely rare

Distribution

Second and third oxidation zones

Paragenesis

Supergene

Entry Number

Species; TSNB256

Type Mineralogy

The discovery of o’danielite is credited to Dr Bruno Geier who was chief mineralogist at Tsumeb between 1952 and 1972. Geier submitted an unidentified secondary mineral in cavities in corroded chalcocite-tennantite ore to Paul Keller for further study. O’danielite, IMA 1979-040, was described by Keller et al. (1981d) and named for Herbert O’Daniel (1903-1977), professor of mineralogy at the University of Munich. The original name, o’Danielite, was officially revised to o’danielite (Burke 2008). The crystal structure was revised by Keller and Hess (1988). Type material is conserved at the Institut für Mineralogie und Kristallchemie, Universität Stuttgart, Germany (catalogue number NM 09); in the Archiv der Universität Stuttgart, (Paul Keller Collection; catalogue number TM-79.40-8701.13) and at the Smithsonian Institution in Washington D.C. (catalogue number 145966).

General Notes

The type assemblage for o’danielite consists of "… a green cuprian adamite [= zincolivenite] as the older mineral. Younger than o’danielite are colourless prosperite … and a pale-rose manganous (sic.) koritnigite" (Keller et al. 1981d). The level from which the type specimen was recovered is not recorded, but it is almost certainly from the second oxidation zone and the paragenesis suggests the East 9 Pillar on 31 Level as a probable source.


O’danielite on the type specimen is transparent, pale violet in colour with a vitreous lustre. It occurs as anhedral grains up to 3 mm in size, sometimes with a tabular habit; euhedral crystals were not observed (Keller et al. 1981d).


Keller and Bartelke (1982) included o'danielite in an extended version of Keller’s (1977) paragenetic sequence II/4 as follows:


conichalcite >> cuprian adamite [=zinolivenite] >> o'danielite >> prosperite >> koritnigite.


A second paragenesis, believed to have been found on 46 Level in the third oxidation zone, comprises green o'danielite, with blue stranskiite, on quartz.