Stibioclaudetite

TSNB331
Mineral
Second oxidation zone (?)Third oxidation zone (?)Supergene
Stibioclaudetite: Slender, colourless, transparent crystals of stibioclaudetite (to 3 mm) with quartz. 15 mm field of view. MGMH Collection 2020.7.774.
Stibioclaudetite: Slender, colourless, transparent crystals of stibioclaudetite (to 3 mm) with quartz. 15 mm field of view. MGMH Collection 2020.7.774.
Image Credit: Malcolm Southwood

Mineral Species

Stibioclaudetite

Type Locality

Yes

Composition

AsSbO3

Crystal System

Monoclinic

Status at Tsumeb

Confirmed (type locality)

Abundance

Very rare

Distribution

Second (?) and third (?) oxidation zones

Paragenesis

Supergene

Entry Number

Species; TSNB331

Type Mineralogy

A specimen of leiteite with ludlockite, quartz, and crystals (to 6 mm) of a colourless unidentified mineral was obtained by the late Bill Pinch (1940-2017) who submitted it for further study. Raman spectroscopy failed to produce a match to any known mineral species and EDS indicated the presence of only antimony and arsenic. Further investigation led to the submission and approval of IMA 2007-028, which was named stibioclaudetite in allusion to its composition and structural relationship with claudetite (Origlieri et al. 2009). Type material is conserved at the Smithsonian Institution in Washington D.C. (catalogue number 174550).

General Notes

The location in the mine from which the type material for stibioclaudetite was recovered is not known precisely. Leiteite has not been recorded in the first oxidation zone but occurs in both the second and third oxidation zones. Based on the observed paragenesis of stibioclaudetite, with leiteite, ludlockite, quartz and smithsonite on a tennantite-rich sulphide matrix, Origlieri et al. (2009) suggested that the type specimen may be from a different occurrence than either the leiteite type assemblage of the second oxidation zone or the "Zinc Pocket" and associated occurrences of the third oxidation zone.


Stibioclaudetite forms colourless, bladed crystals (to 6 mm) with dominant forms {010} and {110}, prominent {111} and very minor {101}; it is transparent with an adamantine lustre (Origlieri et al. 2009).


Stibioclaudetite is readily confused with claudetite or leiteite and analysis is required for certain identification.

Associated Minerals

leiteite; ludlockite; quartz; smithsonite; tennantite-(Zn)